To prepare this espresso pound cake as a gluten-free recipe, substitute the all-purpose flour with a high-quality 1:1 gluten-free baking flour that includes xanthan gum. Maintain the cornstarch in the recipe, as it contributes to a tender crumb. Confirm that the espresso powder and baking powder are certified gluten-free, and bake as directed, checking doneness a few minutes early if needed.